support@kaust.edu.sa
+966 (12) 808-3463
  • العربية
logo-black
  • Home
  • People
    • Current
    • Alumni
    • Group photos 
  • Research
  • Publications
    • 2024
    • 2023
    • 2022
    • 2021
    • 2020
    • 2019
    • 2018
    • 2017
    • 2016
    • Journal covers
  • Internship
  • News
  • KPV-LAB in the press
  • Join us
  • Contact us
breadcrumb-bg

Toward Stable Monolithic Perovskite/Silicon Tandem Photovoltaics: A Six-Month Outdoor Performance Study in a Hot and Humid Climate

  1. Home
  2. Publications
  • Clear filters

Toward Stable Monolithic Perovskite/Silicon Tandem Photovoltaics: A Six-Month Outdoor Performance Study in a Hot and Humid Climate

by Michele De Bastiani, Emmanuel Van Kerschaver, Quentin Jeangros, Atteq ur Rehman, Erkan Aydin, Furkan H. Isikgor, Alessandro J. Mirabelli, Maxime Babics, Jiang Liu, Shynggys Zhumagali, Esma Ugur, George T. Harrison, Thomas G Allen, Bin Chen, Yi Hou, Semen Shikin, Edward H. Sargent, Christophe Ballif, Michael Salvador, Stefaan De Wolf
Letter Year: 2021 DOI: https://doi.org/10.1021/acsenergylett.1c01018

Bibliography

De Bastiani, M., Van Kerschaver, E., Jeangros, Q., Ur Rehman, A., Aydin, E., H. Isikgor, F., J. Mirambelli, A., Babics, M., Liu, J., Zhumagali, S., Ugur, E., T. Harrison, G., G. Allen, T., Chen, B., Hou, Y., Shikin, S., H. Sargent, E., Ballif, C., Salvador, M., De Wolf, S.     

Extra Information

Perovskite solar cells are an emerging photovoltaic technology that is gathering huge attention in the solar community for its power conversion efficiency. Recently, the coupling between the perovskite and the silicon technologies in the tandem configuration boosted even further this power conversion efficiency, reaching record values for terrestrial applications. However, several degradation mechanisms in the perovskite are negatively affecting the stability of this technology, questioning if successful commercialization is possible. At KPVLAB we are pioneering the outdoor testing of perovskite/silicon tandem solar cells to investigate, understand, and improve their stability.

 

Abstract

Perovskite/silicon tandem solar cells are emerging as a high-efficiency and prospectively cost-effective solar technology with great promise for deployment at the utility scale. However, despite the remarkable performance progress reported lately, assuring sufficient device stability—particularly of the perovskite top cell—remains a challenge on the path to practical impact. In this work, we analyze the outdoor performance of encapsulated bifacial perovskite/silicon tandems, by carrying out field-testing in Saudi Arabia. Over a six month experiment, we find that the open circuit voltage retains its initial value, whereas the fill factor degrades, which is found to have two causes. A first degradation mechanism is linked with ion migration in the perovskite and is largely reversible overnight, though it does induce hysteretic behavior over time. A second, irreversible, mechanism is caused by corrosion of the silver metal top contact with the formation of silver iodide. These findings provide directions for the design of new and more stable perovskite/silicon tandems.

Keywords

Degradation Anions Layers Solar cells Perovskites
logo-white

"KAUST shall be a beacon for peace, hope and reconciliation, and shall serve the people of the Kingdom and the world."

King Abdullah bin Abdulaziz Al Saud, 1924 – 2015

Contact Us

    stefaan.dewolf@kaust.edu.sa
  • 4700 King Abdullah University of Science and Technology

    Al-Kindi (building 5), Level 3 Seaside, Right side

    Thuwal 23955-6900

    Kingdom of Saudi Arabia

Tweets by KAUST_KPVLab

© King Abdullah University of Science and Technology. All rights reserved

Privacy Policy
Terms of Use
Loading...