support@kaust.edu.sa
+966 (12) 808-3463
  • العربية
logo-black
  • Home
  • People
    • Current
    • Alumni
    • Group photos 
  • Research
  • Publications
    • 2024
    • 2023
    • 2022
    • 2021
    • 2020
    • 2019
    • 2018
    • 2017
    • 2016
    • Journal covers
  • Internship
  • News
  • KPV-LAB in the press
  • Join us
  • Contact us
breadcrumb-bg

Photo-induced enhancement of lattice fluctuations in metal-halide perovskites

  1. Home
  2. Publications
  • Clear filters

Photo-induced enhancement of lattice fluctuations in metal-halide perovskites

by Mingcong Wang, Yajun Gao, Kai Wang, Jiang Liu, Stefaan De Wolf, Frédéric Laquai
Article Year: 2022 DOI: https://doi.org/10.1038/s41467-022-28532-0

Bibliography

Wang. M., Gao. Y., Wang. K., Liu, J., De Wolf. S., Laquai, F. 

Abstract

The optoelectronic properties of metal-halide perovskites (MHPs) are affected by lattice fluctuations. Using ultrafast pump-probe spectroscopy, we demonstrate that in state-of-the-art mixed-cation MHPs ultrafast photo-induced bandgap narrowing occurs with a linear to super-linear dependence on the excited carrier density ranging from 1017 cm−3 to above 1018 cm−3. Time-domain terahertz spectroscopy reveals carrier localization increases with carrier density. Both observations, the anomalous dependence of the bandgap narrowing and the increased carrier localization can be rationalized by photo-induced lattice fluctuations. The magnitude of the photo-induced lattice fluctuations depends on the intrinsic instability of the MHP lattice. Our findings provide insight into ultrafast processes in MHPs following photoexcitation and thus help to develop a concise picture of the ultrafast photophysics of this important class of emerging semiconductors.
logo-white

"KAUST shall be a beacon for peace, hope and reconciliation, and shall serve the people of the Kingdom and the world."

King Abdullah bin Abdulaziz Al Saud, 1924 – 2015

Contact Us

    stefaan.dewolf@kaust.edu.sa
  • 4700 King Abdullah University of Science and Technology

    Al-Kindi (building 5), Level 3 Seaside, Right side

    Thuwal 23955-6900

    Kingdom of Saudi Arabia

Tweets by KAUST_KPVLab

© King Abdullah University of Science and Technology. All rights reserved

Privacy Policy
Terms of Use
Loading...