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Metal-induced gap states in passivating metal-silicon contacts

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Metal-induced gap states in passivating metal-silicon contacts

by Muhammad Sajjad, Xinbo Yang, Pietro Altermatt, Nirpendra Singh, Udo Schwingenschlögl, Stefaan De Wolf
Letter Year: 2019 DOI: https://doi.org/10.1063/1.5066423

Bibliography

Sajjad, M., Yang, X., Altermatt, P., Singh, N., Schwingenschlögl, U., and De Wolf, S. "Metal-induced gap states in passivating metal/silicon contacts​" Applied Physics Letters 2019 114, 071601.

Abstract

​Passivating metal/silicon contacts combine low carrier recombination with low contact resistivities, enabled by a low gap state density at their interface. Such contacts find applications in high-efficiency solar cells. We perform first-principles calculations based on density functional theory to investigate the surface defect and metal-induced gap state density of silicon in close contact with metals (Al and Ag). We confirm that surface hydrogenation fully removes surface-defect gap states of (111)-oriented silicon surfaces. However, the metal-induced gap state density increases significantly when metals are closer than 0.5 nm to such surfaces. These results highlight the importance of the tunneling-film thickness in achieving effective passivating-contact formation.

Keywords

Semiconductors Density functional theory First-principle calculations passivation
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