Interplay between temperature and bandgap energies on the outdoor performance of perovskite/silicon tandem solar cells

by Erkan Aydin, Thomas G. Allen, Michaele De Bastiani, Lujia Xu, Jorge Ávila, Michael Salvador, Emmanuel Van Kerschaver, Stefaan De Wolf
Article Year: 2020 DOI:


Aydin, E., Allen, T. G., De Bastiani, M., Xu, L.,  Ávila, J., Salvador, M., Van Kerschaver, E., De Wolf, S., Nature Energy 2020.

Extra Information

This study, which took place in Nature Energy, show that a lower bandgap perovskite than needed at standard test conditions is actually beneficial to perovskite/silicon tandem cells in the field.


Perovskite/silicon tandem solar cells promise power conversion efficiencies beyond the Shockley–Queisser limit of single-junction devices; however, their actual outdoor performance is yet to be investigated. Here we fabricate 25% efficient two-terminal monolithic perovskite/silicon tandem solar cells and test them outdoors in a hot and sunny climate. We find that the temperature dependence of both the silicon and perovskite bandgaps—which follow opposing trends—shifts the devices away from current matching for two-terminal tandems that are optimized at standard test conditions. Consequently, we argue that the optimal perovskite bandgap energy at standard test conditions is <1.68 eV for field performance at operational temperatures greater than 55 °C, which is lower compared with earlier findings. This implies that bromide-lean perovskites with narrower bandgaps at standard test conditions—and therefore better phase stability—hold great promise for the commercialization of perovskite/silicon tandem solar cells.


perovskite silicon tandems Field Performance Outdoor test High-efficiency devices Hybrid tandems Certified tandems